Nate and Blair, Gossip Girl xx Wikia

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The relationship Nate and Blair, also known as Blate, is the friendship and former romantic relationship between Nate Archibald and Blair Waldorf. Nate and Blair are together in the first episode, at Blair's birthday party they are very much an item but haven't yet slept together, a fact that means Blair is very worried over her hold of Nate. So when she hears Serena van der Woodsen is back in town she decides to sleep with him to stop him from going off with Serena, who, it is later revealed, h